hntr59 is right, not much you can do. You could try and mislead them, though. For a few days proir to having to give your sample, you could eat tons of poppy seeds, this will sure as hell give a false opiate reading that you can appeal against. On closer examination it is possible to proove the absence of acutal opiates and reduce it down to the consumption of the poppies.
I admit, all a bit risky, depends on how much you need the job, really.
I know, it's not easy, but occasionally one has to stop smoking. (crap idea)
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